Godlike
Xorn (Grandia III) vs Nyarlathotep (Persona 2: Eternal Punishment)- Kneejerk. Nyalie starts with his best damage, feels more durable, is fast enough to not be totally raped on that front.
Tibarn (Fire Emblem: Radiant Dawn) vs Arceus (Pokemon)- Rarr Ghost.
Heavy
Melbu Frahma (Legend of Dragoon) vs Marona (Phantom Brave)- Melbu can, uh, PARALYSE?!?!? Yeah, Marona fights him for a while herself, doesn't bother Confining until he's in his form that can beat stallers.
Levin Brenton (Wild ARMs XF) vs Angeal Hewley (Crisis Core: Final Fantasy VII)- Levin against an average speed enemy can deal along the lines of 4.5x PC before they get a turn. I don't think Angeal is quite that durable to physicals... (Additionally, it's clear now that both these folks are Godlike. Oh well, untested quirk duellers with low voting pool does that.)
Middle
Mog (Final Fantasy VI) vs Junpei Iori (Persona 3)- No vote.
Bow (Breath of Fire II) vs Jessica Philomele (Mana Khemia: Alchemists of Al Revis)- No vote.
Light
Sho Minamimoto (The World Ends With You) vs Kid (Chrono Cross)- I dunno. too tired to vote on this match. Although hyping Kid as stealing Minamimoto's clothes and thus dropping his 40HKO down to god knows what is appealing.
Garnet Sunday (Super Robot Taisen: Original Generation) vs Melody Vilente (Wild ARMs 3)- Yeaaaaaaahhh.